As an important technology for energy digitization,blockchain technology is characterized by distributed computing,storage,data sharing,sharing,openness and transparency,non-tampering and traceability,which can provide technical support for this industry.The deadlock of energy digital economy can be broken by blockchain.The role of blockchain played in building a new production relationship in digital energy economy is analyzed from three aspects:ownership of the means of production,new production relations and product distribution.Meanwhile,based on the new production relationship,there are three application scenarios of blockchain in energy digital economy,namely the metering of energy data,electronic contracts and power outage insurance.By analyzing and summarizing the application scenarios above,it is expounded that the integration of business mode and other digital technologies is key to the research.In the development of blockchain,the storage space and user privacy are the key problems to be solved.